Frequently
Asked Questions - Stainless Steel
1.
What is austenitic, ferritic,
martensitic and duplex
stainless steel?
A. Each of
the terms represent a metallurgical phase
associated with the alloy.
Ferritic
stainless steels must have more than
10-12% chromium to be considered
stainless. This provides the ferrite
phase, or structure, that is strong and
hard. However, this structure cannot be
significantly hardened by further
cold-work or heat treatment.
Martensitic
stainless steels have higher carbon
and chromium contents than the ferritic
stainless steel, plus manganese and
silicon, which allow the formation of hard
acicular (spiky) structures. These alloys
can be hardened, or tempered, by heat
treatment.
Austenitic
stainless steel have chromium and
nickel contents, which provide the
material with excellent corrosion and
malleable (workable) properties at room
temperature.
Duplex
stainless steels have controlled
amounts of ferrite and austenite in their
structures, which allow these alloys to
exhibit higher strengths than their
austenitic counterparts, while retaining
the corrosion resistance of the austenitic
materials. These benefits are achieved
through balanced 50% austenitic and 50%
ferrite structures. They offer good
resistance to chloride ion stress
corrosion cracking. back
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2. Why
is this series of materials called
stainless?
A.
Stainless steel must have at least 10%
chromium in its content to be called
stainless.
Below this value,
the alloy steels will experience
increasing corrosion rates and will begin
to rust in water environments.
18-8 stainless
steel (typically 304), which has 18%
chromium, will exhibit low or negligible
general corrosion rates in water. back
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3. What
are the 18-8's?
A. This
characterizes those materials having 18%
chromium and 8% nickel. These are known as
the 300 series of austenitic stainless
steels.
The more common
of these materials is 304, 304L, 316 and
316L stainless steels, which represent
over 50% of all stainless steels used
today. back to main
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4. What is
the difference between 304 and 304L?
A. The "L" stands for the
low carbon grade (>.03% carbon). This
is the grade of austenitic stainless steel
that should be selected when welding with
these austenitic grades of material. back
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5. What
makes stainless, stainless?
A. The
corrosion resistance of the austenitic
stainless steels is realized through the
tight, adherent oxide scale that forms
naturally on stainless steel surfaces.
Even small amounts of oxygen in the
operating environment will allow stainless
to form this protective scale. It is very
thin (angstroms thick) and consists of
chromium and nickel oxides. back
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6. Can
stainless steel rust?
A. Austenitic stainless steel does not rust.
The presence of rusting on stainless steel
components is due to iron particle
contamination - from lifting gear; welding
spatter; shop dirt; and general lack of
cleanliness. When exposed to moisture or
humidity, the iron particles will corrode
(rust) leaving an undesirable surface
condition on the stainless steel surface,
which under the most severe conditions
could lead to pitting of the stainless
steel surface.
However, this
condition can be readily treated with a
number of acids, followed by thorough
washing to remove the excess acid.
(reference ASTM Specification A380 for
different approaches to cleaning).
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7. Can
stainless steel be magnetic?
A. The
ferritic, martensitic and duplex stainless
steels will be magnetic.
A completely
austenitic stainless steel (type 300
series) will be non-magnetic.
In the case of
welded austenitic stainless steel (type
304L and 316L), a small amount of ferrite
(<5%) may be desired in the weld in
order to eliminate hot short cracking of
the weld. In these cases, a slight
magnetic response of the weld may be
identified.
Also, in severely
worked conditions, some martensitic phases
can be produced which will also provide a
magnetic response. This may be typical in
the precipitation hardened, austenitic
stainless steels.
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8. What
does the S stand for in schedule 10S pipe
sizes?
A. The
pipe schedule (ANSI B36.19) was developed
specifically for stainless steel, to
accommodate instances where corrosion
allowances are not needed. Consequently,
lighter wall thickness can be selected.
Some of the pipe OD and wall sizes are
common with the carbon steel schedules
(reference ANSI B36.10), but as the
diameters increase, there is a divergence
in permissible wall thickness.
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